The fertile-window method
Ovulation typically happens about 14 days before the next period starts, because the luteal phase (after ovulation) is fairly constant. So:
The fertile window is roughly the five days before ovulation plus ovulation day itself — about six days — because sperm can survive several days and the egg lives about a day. Conception is most likely in the two days before ovulation.
Worked example
Last period January 1, 28-day cycle:
Accuracy and limits
This calendar method assumes regular cycles and average luteal length, which isn't true for everyone. Stress, illness and natural variation move ovulation around. Methods like tracking basal body temperature or ovulation predictor kits (which detect the LH surge) are more precise. Use this as a starting estimate, not contraception.